With the increasing interest towards nanoparticle thin films, there is a need for nanoparticle coating technique that can produce monolayers or controlled multi-layered structures on large areas. Spin coating is one of the most used thin-film coating technique and for this reason, any new technique is typically compared to it.
Basics of spin coating
The most typical usage of spin coating is the deposition of photoresist in the semiconductor industry. A photoresist is a light-sensitive polymer compound dispersed into a solvent. The photoresist is dispensed on the substrate with the pipette. A uniform layer with the desired thickness is achieved by the combination of acceleration and constant speed rate sections in the pre-defined spinning recipe.
Basics of Langmuir – Blodgett deposition
Langmuir-Blodgett method has traditionally been used to deposit different types of amphiphilic molecules such as phospholipids and fatty acids. There a monolayer of molecules is first spread on the air-water interface after which the packing density of the monolayer is controlled by decreasing the surface area. Finally, the monolayer is transferred to the solid substrate by dipping.
Spin coating vs. Langmuir-Blodgett for nanoparticle deposition
When it comes to nanoparticles, the Langmuir-Blodgett method offers many advantages over spin coating. First, due to the nature of the spin-coating technique, it requires relatively large amount of nanoparticle solution as some of it will be wasted in the process. In Langmuir-Blodgett method, practically all material can be utilized. Second, Langmuir-Blodgett also offers a well-controlled packing density of the nanoparticles and furthermore, the monolayer quality can be inspected prior the deposition with the technique called Brewster angle microscopy. Multilayer structures can also be produced easily as there can be as many dipping cycles as needed.
Amount of material required
Controlled packing density
Monolayer inspection prior deposition
Controlled multi-layer structures
To read more about Langmuir-Blodgett deposition of nanoparticles, please download the white paper below.
Nanoparticle thin films are finding applications in areas where functional coatings are needed. How to produce these nanoparticle thin film needs to be considered. Dip coating offers one of the simplest methods to coat the substrate with nanoparticles.